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Prof. Dr. R. Beckhaus

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Petra Rösner

W3-3-339

+49 (441) 798 3654

FAX:  +49 (441) 798 3352

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Anschrift und Anfahrt

Dr. Malte Fischer

Institut für Chemie
Universität Oldenburg
Carl-von Ossietzky-Straße 9 - 11
26129 Oldenburg

E-Mail: malte.fischer@uol.de

Tel.: +49(441)798-3658 (Büro)
        +49(441)798-3665 (Labor)

FAX: +49(441)798-3352

Raum: W3-0-163

 

Teaching Experience and Internships

Teaching Experience
2015 – 2019         Advisor and Instructor for Bachelor and Master Students, University of Oldenburg
2013 – 2015         Lecturer and Laboratory Instructor for Undergraduates, University of Oldenburg
2012                     Tutor for the Undergraduate Courses Basic Organic Chemistry
Internships
Summer 2014     Industrial Placement at BÜFA GmbH Co. Kg Oldenburg

 

Education

05/2019 – now             Research Scientist
                                       Carl von Ossietzky University Oldenburg, Germany
                                       Institute of Chemistry
                                       Supervisor: Prof. Dr. Rüdiger Beckhaus
10/2015 – 05/2019      PhD in Organometallic and Coordination Chemistry (Summa Cum Laude)
                                       Title: “Cationic Complexes of Group 4 Metals with Multidentate Ligands – Novel
                                       Syntheses   and Cooperative Reaction Patterns”
                                       Carl von Ossietzky University Oldenburg, Germany
                                       Institute of Chemistry
                                       Supervisor: Prof. Dr. Rüdiger Beckhaus, Co-Advisor: Prof. Dr. Uwe Rosenthal
10/2013 – 10/2015      Master of Science (M.Sc.) in Organometallic and Coordination Chemistry (final
                                       grade: 1.0, with distinction)
                                       Title of the master thesis: “Synthesis and Reactivity of Bis(benzofulvene)titanium
                                       Complexes”
                                      Carl von Ossietzky University Oldenburg, Germany
                                      Institute of Chemistry
                                      Supervisor: Prof. Dr. Rüdiger Beckhaus, Co-Advisor: Prof. Dr. Thomas Müller
10/2010 – 10/2013     Bachelor of Science (B.Sc.) in Organic Chemistry (final grade: 1.5)
                                      Title of the bachelor thesis: “Multicomponent Reactions for the Syntheses of
                                      Annulated Valerolactams”
                                      Carl von Ossietzky University Oldenburg, Germany
                                      Institute of Chemistry
                                      Supervisor: Prof. Dr. Jürgen Martens

 

Awards and Achievements

03/2019      Oral Presentation Award, 21st JCF Frühjahrssymposium/ 2nd European Young Chemists Meeting,
                     Bremen.
09/2018      Oral Presentation Award, 21st Norddeutsches Doktorandenkolloquium, Braunschweig.
09/2017      Dalton Transactions Poster Prize, 20th Norddeutsches Doktorandenkolloquium, Kiel.
01/2016      Award for the outstanding master thesis by the „Fakultät für Mathematik und Naturwissenschaften“.
10/2015      Award for outstanding student performance by the GDCh (Gesellschaft Deutscher Chemiker).

Publications

15. M. Fischer, D. Barbul, M. Schmidtmann, R. Beckhaus, "Unexpected Selective Methyl Group Abstractions from SiMe3 Moieties of CH2SiMe3 Ligands to Give New Cationic Titanium Complexes.” Chem. Eur. J. 2019, in press; DOI: 10.1002/chem.201900599.
    • Featured on the frontispiece
14. M. Fischer, M. Schmidtmann, R. Beckhaus, “To Coordinate or not to Coordinate: The Special Role of Chalcogen Ether Functionalities in the Design of Twofold Functionalized Cyclopentadienyl Ligands [Cp,O,Ch (Ch = S, Se)].” Z. Anorg. Allg. Chem. 2019, 645, 595-605; DOI: 10.1002/zaac.201900012.
13. T. Oswald, M. Fischer, N. Struckmann, M. Schmidtmann, R. Beckhaus, “Reaction of Pentafulvene Titanium and Zirconium Complexes with Phosphorus Ylides: Stoichiometric Reactions and Catalytic Intramolecular Proton Shuttles.” Organometallics 2019, 38, 829-843; DOI: 10.1021/acs.organomet.8b00831.
12. M. Fischer, K. Schwitalla, S. Baues, M. Schmidtmann, R. Beckhaus, “FLP Behaviour of Cationic Titanium Complexes with Tridentate Cp,O,N-Ligands: Highly Efficient Syntheses and Activation Reactions of C–X bonds (X = Cl, F).” Dalton Trans. 2019, 48, 1516-1523; DOI: 10.1039/C8DT04707C.
11. M. Fischer, H. Steinert, M. Schmidtmann, R. Beckhaus, “Teaching c-Phosphanylimines the Titanaaziridine Coordination Mode.“ Dalton Trans. 2019, 48, 1936-1940; DOI: 10.1039/C8DT04918A.
    • Featured on the inside back cover
10. M. Fischer, M. Jaugstetter, R. Schaper, M. Schmidtmann, R. Beckhaus, “Cationic Group 4 Complexes (M = Ti, Zr, Hf): Modifications and Limitations in the Design of Tridentate Cp,O,P-Ligand Frameworks Built Directly in the Coordination Sphere of the Metal.” Eur. J. Inorg. Chem. 2018, 5146-5159; DOI: 10.1002/ejic.201801016.
    • Featured on the front cover
    • “very important paper”
    • Invited cover profile; DOI: 10.1002/ejic.201801455.
9. M. Fischer, D. Barbul, M. Schmidtmann, R. Beckhaus, “Convenient Synthesis of Cationic Titanium Complexes with Tridentate Cp,N,P-Ligand Framework: FLP-Like Reactivity at the Ti–N Bond and Unexpected Ligand Hydrogenation Reaction.” Organometallics 2018, 37, 1979-1991; DOI: 10.1021/acs.organomet.8b00283.
8. M. Fischer, R. Schaper, M. Jaugstetter, M. Schmidtmann, R. Beckhaus, “Electrophilic d0 Cations of Group 4 Metals (M = Ti, Zr, Hf) Derived from Monopentafulvene Complexes: Direct Formation of Tridentate Cp,O,P-Ligands.” Organometallics 2018, 37, 1192-1205; DOI: 10.1021/acs.organomet.8b00088.
7. M. Fischer, T. Oswald, H. Ebert, M. Schmidtmann, R. Beckhaus, “Expanding the Scope: Monopentafulvene and –Benzofulvene Complexes of Zirconium and Hafnium.” Organometallics 2018, 37, 415-421; DOI: 10.1021/acs.organomet.7b00832.
6. M. Fischer, M. Schmidtmann, R. Beckhaus, “Crystal Structure of the η4-Ketimine Titanium Complex (Diphenylamido-κN){3-methyl-6-[(4-methylphenyl)(phenylazanidyl)methylidene]cyclohexa-2,4-dien-1-yl-κ2N,C1}(η5-pentamethylcyclopentadienyl)titanium(IV).” Acta Cryst. E 2018, E74, 34-37; DOI: 10.1107/S2056989017017455.
5. M. Manßen, I. Weimer, C. Adler, M. Fischer, M. Schmidtmann, R. Beckhaus, “From Organic Azides Through Titanium Triazenido Complexes to Titanium Imides.” Eur. J. Inorg. Chem. 2018, 131-136; DOI: 10.1002/ejic.201701273.
4. M. Fischer, M. Schmidtmann, R. Beckhaus, “Crystal Structure of the Formal 20 Electron Zirconocene Pentafulvene Complex Cp2Zr(η51-adamantylidenepentafulvene):toluene:n-hexane = 1:0.125:0.125.” Acta Cryst. E 2017, E73, 1823-1826; DOI: 10.1107/S2056989017015560.
3. M. Fischer, M. Schmidtmann, R. Beckhaus, “From Five to Five: Titanium Ketimine Complexes with Monoazabutadiene η4-Coordination Mode and Hidden η2-Imine Reactivity.” Organometallics 2017, 36, 4779-4793; DOI: 10.1021/acs.organomet.7b00673.
    • Featured on the front cover
2. F. Jaroschik, M. Penkhues, B. Bahlmann, M. Fischer, E. Nicolas, F. Massicot, A. Martinez, D. Harakat, M. Schmidtmann, K. V. Radhakrishnan, J.-L. Vasse, R. Beckhaus, “Synthesis, Characterization and Reactivity of Formal 20 Electron Zirconocene-Pentafulvene Complexes.” Organometallics 2017, 36, 2004-2013; DOI: 10.1021/acs.organomet.7b00213.
1. D. Kröger, T. Schlüter, M. Fischer, I. Geibel, J. Martens, “Three-Component Reaction Toward Polyannulated Quinazolinones, Benzoxazinones and Benzothiazinones.” ACS Comb. Sci. 2015, 17, 202-207; DOI: 10.1021/CO500165A.

Cover Pictures

Conference Contributions

Oral Presentations
5. “Electrophilic Complexes of Group 4 Metals: Establishing Novel Types of Tridentate Ligands and their Applications”, 21st JCF Frühjahrssymposium/ 2nd European Young Chemists Meeting, Bremen 2019.
4. “Teaching the CH2SiMe3 Moiety New Tricks: Selective Methyl Group Abstraction at the SiMe3 Unit to Give Novel Cationic Titanium Complexes”, Seminar on Chemical Bond Activation, DFG Graduate School 2226, Oldenburg 2019.
3. “Monopentafulvene Complexes of Group 4 Metals as Efficient Precursor Complexes for tm-FLPs”, Tag der Chemie, Oldenburg 2018.
2. “Monopentafulvene Complexes of Group 4 Metals as Highly Versatile and Efficient Precursors for Cationic Complexes and their Applications as tm-FLPs”, 21st Norddeutsches Doktorandenkolloquium, Braunschweig 2018.
1. “Cationic Complexes of Group 4 with Tridentate Cp,E,P-Ligands (E = O, N): Synthetic Strategies and Applications in tm-FLP Chemistry”, 14th Koordinationschemie-Treffen, Heidelberg 2018.

Poster Presentations
3. “From Five to Five: Titanium Ketimine Complexes with η4-Monoazabutadiene Coordination Mode and Hidden η2-Imine Reactivity”, Kiel 2017.
2. “Synthesis and Reactivity of Bis(η51-benzofulvene)titanium Complexes”, Wöhler-Tagung, Berlin 2016.
1. “Synthesis and Reactivity of Bis(η51-benzofulvene)titanium Complexes”, 20th Norddeutsches Doktorandenkolloquium , Hamburg 2016.

References

Prof. Dr. Rüdiger Beckhaus
Department of Chemistry
University of Oldenburg
D-26111 Oldenburg, Germany
E-mail: ruediger.beckhaus@uol.de
Tel: +49 (0)-441/798-3656

Prof. Dr. Uwe Rosenthal
Leibniz-Institut für Katalyse e.V.
D-18059 Rostock, Germany
E-mail: uwe.rosenthal@catalysis.de
Tel: +49 (0)-381/1281-176
Prof. Dr. Jürgen Martens
Department of Chemistry
University of Oldenburg
D-26111 Oldenburg, Germany
E-mail: juergen.martens@uol.de
Tel: +49 (0)-441/798-3837
 
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