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Selectivity of Radical Reactions (Selektivität von Radikalreaktionen).

Publikationen Radikalchemie

Wichtige Publikationen zum Forschungsschwerpunkt Radikalchemie:

  • Michael Blumenstein, Matthias Lemmler, Ahlke Hayen, and Jürgen O. Metzger, Enantioselective Hydrogen Transfer Reactions from Chiral Binaphthyl Variants of Tin Hydrides to Prochiral Radicals, Tetrahedron Asym., 2003, 3069-3077, fulltext.

  • Jens Griep-Raming, Sven Meyer, Torsten Bruhn, Jürgen O. Metzger, Investigation of Reactive Intermediates of Chemical Reactions in Solution by Electrospray Ionization Mass Spectrometry: Radical Chain Reactions, Angew. Chem. 2002, 114, 15 2863-2866, fulltext (de); Angew. Chem. Int. Ed. 2002, 41, 15, 2738-2742, fulltext (engl.).
  • Ahlke Hayen, Rainer Koch, Wolfgang Saak, Detlef Haase, Jürgen O. Metzger, 1,3-Stereoinduction in Radical Reactions: Radical Additions to Dialkyl 2-Alkyl-4-methyleneglutarates, J. Am. Chem. Soc. 2000, 122, 12458-12468, fulltext.

  • A. Hayen, R. Koch, J.O. Metzger, 1,3-Stereoinduction in Radical Reactions, Angew. Chem. 2000, 112, 2898-2900 Angew. Chem. Int. Ed. 2000, 39, 2758-2761, fulltext.

  • K. Schwarzkopf, M. Blumenstein, A. Hayen and J.O. Metzger, Enantioselectivity of the Transfer of Hydrogen Atoms to Acyclic Prochiral Carbon-Centred Radicals Using Chiral Tin Hydrides, Eur. J. Org. Chem. 1998, 177-181, fulltext.

  • J.O. Metzger, R. Mahler and G. Francke, Radical Additions of Alkyl 2-Haloalkanoates and 2-Haloalkanenitriles to Alkenes Initiated by Electron Transfer from Copper in Solvent-Free Systems, Liebigs Ann./Recueil 1997, 2303-2313, fulltext.

  • K. Schwarzkopf, J.O. Metzger, W. Saak and S. Pohl, Synthesis of Novel Optical Active Tin Hydrides Containing Chiral Ligands, Chem. Ber./Recueil 1997, 1539-1546, fulltext.

  • M. Blumenstein, K. Schwarzkopf und J.O. Metzger, Enantioselective Hydrogen Transfer from a Chiral Tin Hydride to a Prochiral Carbon-Centered Radical , Angew. Chem. 1997, 107, 245-247, fulltext(de); Angew. Chem. Int. Ed. Engl. 1997, 107, 235-236, fulltext(engl.).

  • J.O. Metzger, Ralf Mahler and Andreas Schmidt, Electron Transfer Initiated Free Radical Additions of Perfluoroalkyl Iodides and Diiodides to Alkenes, Liebigs Ann. 1996, 693-696, fulltext.

  • J.O. Metzger and Ralf Mahler, Radical Additions of Activated Haloalkanes to Alkenes Initiated by Electron Transfer from Copper on Solvent-Free Systems, Angew. Chem. 1995, 107, 1012-1015, fulltext(de); Angew. Chem. Int. Ed. Engl. 1995, 34, 902-904, fulltext(engl.).

  • J.O. Metzger and Fritz Bangert, Ane Additions to Unsaturated Fatty Compounds: Thermally Initiated Additions of Alkanes to Methyl 10-Undecenoate, Fat Sci. Technol. 1995, 97, 7-9, fulltext.

  • J.O. Metzger, K. Schwarzkopf, W. Saak and S. Pohl, Stereoselectivity of the Transfer of Hydrogen Atoms to Cyclic Alkyl Radicals, Chem. Ber. 1994, 127, 1-5, fulltext.

  • J.O. Metzger and F. Bangert, Kinetics of the Addition of Cyclohexane to Phenylethyne under Supercritical Fluid Conditions, Chem. Ber. 1994, 127, 1-4, fulltext.

  • J. O. Metzger und M. Blumenstein, Stereoselectivity of the Thermally Initiated Free-Radical Chain Addition of Cyclohexane to 1-Alkynes, Chem. Ber., 1993, 126, 2493-2499, fulltext.

  • B. Giese, H. Farshchi, J. Hartmanns und J.O. Metzger, Isoselective Relationship for the Stereoselectivity of the Transfer of Hydrogen Atoms to Cyclic Alkyl Radicals, Angew. Chem., 103 (1991) 619, fulltext(de); Angew. Chem. Int. Ed. Engl. 30 (1991) 600-601, fulltext(engl.).

  • J.O. Metzger, Addition of Cyclohexane to 1-Octene in a Free radical Chain Reaction at Supercritical Fluid Conditions, J. Prakt. Chem., 332, 767 (1990), fulltext.

  • J.O. Metzger und K. Klenke, Investigations on the Selectivity of the b-Scission of Alkyl Radicals, II - Selectivity of the b-Fragmentation of a-(Methoxycarbonyl)alkyl Radicals, Chem. Ber. 123, 875 (1990), fulltext.

  • K. Klenke und J.O. Metzger, The Influence of Polar and Steric Effects on the Selectivity of the b-Cleavage of Alkyl Radicals, Angew. Chem. 100, 1195 (1988), fulltext(de); Angew. Chem. Int. Ed. Engl. 27, 1168 (1988), fulltext(engl.).

  • B. Giese, J.A. Gonzales-Gomez, St. Lachhein und J.O. Metzger, Influence of H-Donor and Temperature on the Stereoselectivity of Radical Reactions, Angew. Chem. 99, 475 (1987), fulltext(de); Angew. Chem. Int. Ed. Engl. 26, 479 (1987), fulltext(engl.).

  • D. Malwitz und J.O. Metzger, Thermally Induced Redox Reaction of Carbonyl Compounds and Alcohols in a Radical Chain Reaction, Chem. Ber. 119, 3558 (1986), fulltext.

  • D. Malwitz und J.O. Metzger, Thermally Induced Redox Reaction of Carbonyl Compounds and Alcohols in a Radical Chain Reaction: Comproportionation to Two Hydroxyalkyl Radicals, Angew. Chem. 98, 747 (1986), fulltext(de); Angew. Chem. Int. Ed. Engl. 25, 762 (1986), fulltext(engl.).

  • J.O. Metzger, Formation of Alkyl Radicals by Thermal Bimolecular Reaction of Alkanes and Alkenes, Angew. Chem. 95, 915 (1983), fulltext(de); Angew. Chem. Int. Ed. Eng. 22, 889 (1983); Angew. Chem. Suppl. 1983, 1256, fulltext(engl.).


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