Contact

Speaker

Prof. Dr. Sven Doye

Deputy Speaker

Prof. Dr. Rüdiger Beckhaus

Coordination

Sonja Weiz

Publications

2021

60.

J. Strehl, G. Hilt
"Synthesis of Symmetrical and Unsymmetrical Thiosulfonates from Disulfides via Electrochemical Induced Disulfide Bond Metathesis and Site-Selective Oxidation"
Eur. J. Org. Chem. 2021, accepted.
DOI: 10.1002/ejoc.202101007

 

59.

L. Li, S. Kail, S. M. Weber, G. Hilt
"Indium-Catalysed Transfer-Hydrogenation for the Reductive Cyclisation of 2-Alkynyl Enones towards Trisubstituted Furans"
Angew. Chem.; Angew. Chem. Int. Ed., 2021, accepted.
DOI: 10.1002/ange.202109266
DOI: 10.1002/anie.202109266
 

58. F. Balzaretti, M. von Einem, L. Gerhards, W. Dononelli, T. Stauch, T. Klüner, S. Köppen "Charge-Transfer Promoted Fixation of Glyphosate on TiO2 - a Multiscale Approach" ChemRxiv 2021, DOI: 10.26434/chemrxiv.14465436.v1
 
57. N. Mitschke, G. Eruçar, M. H. Fsadni, A. R. Roberts, M. M. Sadeghi, B. T. Golding, J. Christoffers, H. Wilkes
"Enantiopure 2,9-Dideuterodecane – Preparation and Proof of Enantiopurity"
Eur. J. Org. Chem. 2021, 27, 3854-3863.
DOI: 10.1002/ejoc.202100360
 
56.

L. Gerhards, T. Klüner
"Quantum Chemical Investigation of Photocatalytical Sulfoxidation of Hydrocarbons on TiO2"

J. Phys. Chem. C 2021, 125, 13313-13323.

DOI: 10.1021/acs.jpcc.1c03377

 

55.

J. Kräuter, K. Al-Shamery
"Bulk defect-dependent initial steps of acetone oxidation on rutile TiO2(110)"

Mol. Phys. 2021,
DOI: 10.1080/00268976.2021.1963870

 

54.

J. Strehl, M. L. Abraham, G. Hilt
"Linear Paired Electrolysis - Realizing 200% Current Efficiency for Stochiometric Transformations - The Electrochemical Bromination of Alkenes"

Angew. Chem. 2021, 113, 10084-10088; Angew. Chem. Int. Ed. 2021, 60, 9996-10000.
DOI:
10.1002/ange.202016413; 10.1002/anie.202016413
 

53.

A. R. Silva Olaya, B. Zandersons, G. Wittstock
"Effect of the Residual Silver and Adsorbed Lead Anions towards the Electrocatalytic Methanol Oxidation on Nanoporous Gold in Alkaline Media"

Electrochim. Acta 2021, 383C, 138348.
DOI: 10.1016/j.electacta.2021.138348
 

52.

L. Li, G. Hilt
"Indium Tribromide-Catalysed Transfer-Hydrogenation: Expanding the Scope of the Hydrogenation and of the Regiodivergent DH or HD Addition to Alkenes"
Chem. Eur. J. 2021, 27, 11221-11225.
DOI: 10.1002/chem.202101259
 

51.

L. Mohrhusen, L. Gerhards, D. Hirsch, T. Klüner, K. Al-Shamery
"Multidentate Interaction of Methylamine with Rutile TiO2(110)"
J. Phys. Chem. C 2021, 125, 11975−11986.
DOI: 10.1021/acs.jpcc.1c02166
 

50.

L. Mohrhusen, J. Kräuter, K. Al-Shamery
"Conversion of Methanol on Rutile TiO2 (110) and Tungsten Oxide Clusters: 2. The Role of Defects and Electron Transfer in Bifunctional Oxidic Photocatalysts"
Phys. Chem. Chem. Phys. 2021, 23, 12148-12157.
DOI: 10.1039/D1CP01176F
 

49.

L. Mohrhusen, K. Al-Shamery
"Conversion of Methanol on Rutile TiO2 (110) and Tungsten Oxide Clusters: 1. Population of Defect-Dependent Thermal Reaction Pathways"
Phys. Chem. Chem. Phys. 2021, 23, 12137-12147.
DOI: 10.1039/D1CP01175H
 

48.

I. Maack, M. Osmić, L. Mohrhusen, P. Buhani, K. Al-Shamery
"Fitting A Square Peg into A Round Hole: Shape Control in Phase Transfer of Cubic Gold Nanoparticles"
ChemNanoMat 2021, 7, 658-671.
DOI: 10.1002/cnma.202100080
 

47.

D. Geik, M. Rosien, J. Bielefeld, M. Schmidtmann, S. Doye
"Titanium-Catalyzed Hydroaminoalkylation of Alkenes with Tertiary Amines"
Angew. Chem. 2021, 133, 10024-10028; Angew. Chem. Int. Ed. 2021, 60, 9936-9940.
DOI: 10.1002/ange.202100431; 10.1002/anie.202100431

46.

M. Warsitz, S. H. Rohjans, M. Schmidtmann, S. Doye
"Hydroaminoalkylation/Buchwald-Hartwig Amination Sequences for the Synthesis of Novel Thieno- or Benzothieno-Annulated Tetrahydropyridines, Tetrahydroazasilines, and Tetrahydroazasilepines"
Eur. J. Org. Chem. 2021, 5, 830-849.
DOI: 10.1002/ejoc.202001523

45.

J. Weiten, K. Kalvelage, P. Becker, R. Reinhardt, T. Hurek, B. Reinhold-Hurek, R. Rabus
"Complete Genomes of the Anaerobic Degradation Specialists Aromatoleum petrolei ToN1T and Aromatoleum bremense PbN1T"
Microb. Physiol. 2021, 31, 16-35.
DOI: 10.1159/000513167

44.

J. Kräuter, L. Mohrhusen, F. Waidhas, O. Brummel, J. Libuda, K. Al-Shamery "Photoconversion of 2-Propanol on Rutile Titania: A Combined Liquid-Phase and Surface Science Study"
J. Phys. Chem. C 2021, 125, 3355-3367.
DOI: 10.1021/acs.jpcc.0c10734

43.

T. Kaper, M. Fischer, H. Thye, D. Geik, M. Schmidtmann, R. Beckhaus, S. Doye
"Intermolecular Hydroaminoalkylation of Alkynes"
Chem. Eur. J. 2021, 27, 6899-6903.
DOI: 10.1002/chem.202100238

42.

J. P. Hildebrand, M. Weers, V. Lührs, D. H. Taffa, M. Wark
"Metal-free photocatalysts" in "Heterogeneous Photocatalysis: From Fundamentals to Application in Energy Conversion and Depollution"
(Ed.: J. Strunk), Wiley-VCH, Weinheim, 2021.
ISBN: 978-3-527-34464-2

2020

41.

J. Strehl, C. Kahrs, T. Müller, G. Hilt, J. Christoffers
"Electrochemical Induced Ring Transformation of Cyclic α-(ortho-Iodophenyl)-β-oxoesters"
Chem. Eur. J. 2020, 26, 3222-3225.

DOI: 10.1002/chem.201905570
 

40.

J. Strehl, G. Hilt
"Electrochemical, Iodine-Mediated α-CH Amination of Ketones by Umpolung of Silyl Enol Ethers"
Org. Lett. 2020, 20, 5968-5972.

DOI: 10.1021/acs.orglett.0c02068
 

39.

A. R. Silva Olaya, B. Zandersons, G. Wittstock
"Restructuring of nanoporous gold surfaces during electrochemical cycling in acidic and alkaline media"

ChemElectroChem 2020, 7, 3670-3678.

DOI: 10.1002/celc.202000923
 

38.

J. Küppers,# N. Mitschke,# S. Heyen, R. Rabus, H. Wilkes, J. Christoffers
"Metabolites of the Anaerobic Degradation of n-Hexane by Denitrifying Betaproteo­bacterium Strain HxN1"
ChemBioChem. 2020, 21, 373-380.

DOI: 10.1002/cbic.201900375

37.

J. Küppers, N. Mitschke
"Über den Anaeroben Abbau von Kohlenwasserstoffen in Bakterien"
Mitt. Umweltchem. Ökotox. 2020, 3, 85-89.

Download on the GDCh Website

36.

L. Mohrhusen, M. Grebien, K. Al-Shamery
"Electron Transfer in Oxide–Oxide Cocatalysts: Interaction of Tungsten Oxide Clusters with Ti3+ States in Rutile TiO2"
J. Phys. Chem. C 2020, 124, 23661-23673.

DOI: 10.1021/acs.jpcc.0c06591

35.

A. Markovic,# L. Gerhards,# P. Sander, C. Dosche, T. Klüner, R. Beckhaus, G. Wittstock
"Electronic Transitions in Different Redox States of Trinuclear 5,6,11,12,17,18
Hexa­aza­tri­naphthyleneBridged Titanium Complexes: Spectroelectrochemistry and Quantum Chemistry"
ChemPhysChem 2020, 21, 2506-2514.

DOI: 10.1002/cphc.202000547

34.

M. Rosien, I. Töben, M. Schmidtmann, R. Beckhaus, S. Doye
"Titanium
Catalyzed Hydroaminoalkylation of Ethylene"
Chem. Eur. J. 2020, 26, 2138-2142.

DOI: 10.1002/chem.201904502

33.

M. Warsitz, S. Doye
"Linear Hydroaminoalkylation Products from Alkyl-Substituted Alkenes"
Chem. Eur. J. 2020, 26, 15121-15125.

DOI: 10.1002/chem.202003223

32.

M. Warsitz, S. Doye
"Two-Step Procedure for the Synthesis of 1,2,3,4-Tetrahydroquinolines"
Eur. J. Org. Chem. 2020, 45, 6997-7014.

DOI: 10.1002/ejoc.202001337

31.

T. Kaper, M. Fischer, M. Warsitz, R. Zimmering, R. Beckhaus, S. Doye
"Intermolecular Hydroaminoalkylation of Propadiene"
Chem. Eur. J. 2020, 26, 14300-14304.

DOI: 10.1002/chem.202003484

30.

L. Li, G. Hilt
"Regiodivergent DH or HD Addition to Alkenes: Deuterohydrogenation vs. Hydrodeuterogenation"
Org. Lett. 2020, 22, 1628-1632.

DOI: 10.1021/acs.orglett.0c00213

29.

N. Mitschke, J. Christoffers, H. Wilkes
"A Straightforward Synthesis of Trideuterated
αTerpinene for Mechanistic Studies"
Eur. J. Org. Chem. 2020, 31, 4893-4899.

DOI: 10.1002/ejoc.202000684

28.

N. Mitschke, R. Jarling, R. Rabus, J. Christoffers, H. Wilkes
"Metabolites of the anaerobic degradation of diethyl ether by denitrifying betaproteobacterium strain HxN1"

Org. Biomol. Chem. 2020, 18, 7098-7109.

DOI: 10.1039/D0OB01419B

27.

A. Markovic, L. Buschbeck, I. Brand, C. Dosche, J. Christoffers, G. Wittstock
"Electrochemical Activation of Self-Assembled Monolayers for the Binding of Effectors"
Langmuir 2020, 36, 14623-14632.

DOI: 10.1021/acs.langmuir.0c02426

26.

J. Aher, A. Graefenstein G. Deshmukh, K. Subramani, B. Krueger, M. Haensch, J. Schwenzel, K. Krishnamoorthy, G. Wittstock
"Effect of Aromatic Rings and Substituent on the Performance of Lithium Batteries with Rylene Imide Cathodes"
ChemElectroChem 2020, 7, 1160-1165.

DOI: 10.1002/celc.202000118

25.

M. Haensch, M. Graf, W. Wang, A. Nefedov, C. Wöll, J. Weissmüller, G. Wittstock
"Thermally Driven Ag–Au Compositional Changes at the Ligament Surface in Nanoporous Gold: Implications for Electrocatalytic Applications"
ACS Appl. Nano Mater. 2020, 3, 2197-2206.

DOI: 10.1002/celc.202000118

24.

M. Siemer, G. Tomaschun, T. Klüner, P. Christopher, K. Al-Shamery
"Insights into Spectator-Directed Catalysis: CO Adsorption on Amine-Capped Platinum Nanoparticles on Oxide Supports"
ACS Appl. Mater. Interfaces 2020, 12, 27765-27776.

DOI: 10.1021/acsami.0c06086

2019

23. J. Strehl, G. Hilt
"Electrochemical, Manganese-Assisted Carbon-Carbon Bond Formation between β-Keto Esters and Silyl Enol Ethers"
Org. Lett. 2019, 21, 5259-5263.
DOI: 10.1021/acs.orglett.9b01866
 

22.

J. Küppers, P. Becker, R. Jarling, M. Dörries, N. Cakić, M. Schmidtmann, J. Christoffers, R. Rabus, H. Wilkes
"Stereochemical Insights into the Anaerobic Degradation of 4-Iso­propyl­benzoyl-CoA in the Denitrifying Bacterium Strain pCyN1"
Chem. Eur. J. 2019, 25, 4722-4731.

DOI: 10.1002/chem.201805837

21.

J. Küppers, J. Christoffers, R. Rabus, H. Wilkes
"Optically Active 1-Deuterio-1-phenylethane – Preparation and Proof of Enantiopurity"
Eur. J. Org. Chem. 2019, 2629-2634.

DOI: 10.1002/ejoc.201900121

20.

M. Osmić, L. Mohrhusen, K. Al-Shamery
"Bulk defect dependence of low temperature partial oxidation of methanol and high temperature hydrocarbon formation on rutile TiO2 (110)"
J. Phys. Chem. C 2019, 123, 7615-7626.

DOI: 10.1021/acs.jpcc.8b02953

19.

J. Kräuter, L. Mohrhusen, M. Willms, K. Al-Shamery
"Activation of small organic molecules on Ti2+-rich TiO2 Surfaces: Deoxygenation vs. C‑C Coupling"
Z. Naturforsch. 2019, 74, 697-707.

DOI: 10.1515/zna-2019-0135

18.

L. Mohrhusen, J. Kräuter, M. Willms and K. Al-Shamery
"Argon Embedded by Ion Bombardment: Relevance of Hidden Dopants in Rutile TiO2"
J. Phys. Chem. C 2019, 123, 20434-20442.

DOI: 10.1021/acs.jpcc.9b05975

17.

X. Gong, J. Chen, S. Li, L. Mohrhusen, K. Al-Shamery, P. S. Lee
"Vanadium oxide nanosheets for flexible dendrite-free hybrid Al-Li-ion batteries with excellent cycling performance"
Batter. Supercaps 2019, 2, 205-212.

DOI: 10.1002/batt.201800108

16.

J. Chen, L. Mohrhusen, G. Ali, S. Li, K. Y. Chung, K. Al-Shamery, P. S. Lee "Electrochemical mechanism investigation of Cu2MoS4 hollow nanospheres for fast and stable sodium ion storage"
Adv. Funct. Mater. 2019, 29, 1807753-1807765.

DOI: 10.1002/adfm.201807753

15.

L. Buschbeck, A. Markovic, G. Wittstock, J. Christoffers
"Diaminoterephthalate-α-lipoic acid-conjugates with fluorinated residues"
Beilstein J. Org. Chem. 201915, 981-991.

DOI: 10.3762/bjoc.15.96

14.

A. Markovic, L. Buschbeck, T. Klüner, J. Christoffers, G. Wittstock
"Electron transfer and electron excitation processes in derivatives 2,5-diamino­terephthalate derivatives with versatile functionalization"
Chem. Open 20198, 1176-1182.

DOI: 10.1002/open.201900138

13.

M. Haensch, L. Balboa, M. Graf, A. R. Silva Olaya, J. Weissmüller, G. Wittstock
"Mass Transport in Porous Electrodes Studied by Scanning Electrochemical Microscopy: Example of Nanoporous Gold"
ChemElectroChem 2019, 6, 3160-3166.

DOI: 10.1002/celc.201900634

12.

W. Dononelli, G. Tomaschun, T. Klüner, L. V. Moskaleva
"Understanding Oxygen Activation on Nanoporous Gold"
ACS Catal. 2019, 9, 5204-5216.

DOI: 10.1021/acscatal.9b00682

11.

S. Dery, S. Kim, G. Tomaschun, D. Haddad, A. Cossaro, A. Verdini, L. Floreano, T. Klüner, F. D. Toste, E. Gross
"Flexible NO 2 Functionalized NHeterocyclic Carbene Monolayers on Au (111) Surface"
Chem. – A Eur. J. 2019, 25, 15009-15009.

DOI: 10.1002/chem.201903434

10.

S. Dery, S. Kim, G. Tomaschun, I. Berg, D. Feferman, A. Cossaro, A. Verdini, L. Floreano, T. Klüner, F. D. Toste, E. Gross
"Elucidating the influence of anchoring geometry on the reactivity of NO2-functionalized N-heterocyclic carbene monolayers"
J. Phys. Chem. Lett. 2019, 10, 5099-5104.

DOI: 10.1021/acs.jpclett.9b01808

9.

G. Tomaschun, T. Klüner
"Methanol oxidation on the Pt(321) surface: a theoretical approach on the role of surface morphology and surface coverage effects"
Phys. Chem. Chem. Phys. 2019, 21, 18227-18239.

DOI: 10.1039/C9CP03291F

8.

S. Neumann, J. Schröder, F. Bizzotto, M. Arenz, A. Dworzak, M. Oezaslan, M. Bäumer, S. Kunz
"Halide-induced Leaching of Pt Nanoparticles – Manipulation of Particle Size by Controlled Ostwald Ripening"
ChemNanoMat 2019, 5, 462-471.

DOI: 10.1002/cnma.201800550

7.

F. Bizzotto, J. Quinson, A. Zana, J.J.K. Kirkensgaard, A. Dworzak, M. Oezaslan, M. Arenz
"Ir nanoparticles with ultrahigh dispersion as oxygen evolution reaction (OER) catalysts: synthesis and activity benchmarking"     
Catal. Sci. Technol. 2019, 9, 6345-6356.

DOI: 10.1039/C9CY01728C

2018

6.

A. Kohlsdorf, D. H. Taffa, M. Wark
"Microwave assisted synthesis of Ta2O5 nanostructures for photocatalytic hydrogen production"
J. Photoch. Photobiol. A 2018, 366, 41-47.

DOI: 10.1016/j.jphotochem.2018.03.036

5.

H. Kollmann, M. Esmann, J. Witt, A. Markovic, V. Smirnov, G. Wittstock, M. Silies, C. Lienau
"Fourier-Transform Spatial Modulation Spectroscopy of Single Gold Nanorods"
Nanophotonics 2018, 7, 715-726.

DOI: 10.1515/nanoph-2017-0096

4.

M. Siemer, L. Mohrhusen, M. Grebien, K. Al-Shamery
"Amine capped gold colloids at oxidic supports: Their electronic interactions"
Z. Phys. Chem. 2018, 233, 69-84.

DOI: 10.1515/zpch-2018-0004

3.

P. Sander, A. Markovic, M. Schmidtmann, O. Janka, G. Wittstock, R. Beckhaus "Synthesis, Crystal structures, Magnetic and Electrochemical Properties of Highly Phenyl substituted Trinuclear 5,6,11,12,17,18-Hexaazatrinaphthylene (HATNPh6)-bridged Titanium Complexes"
Inorg. Chem. 2018, 57, 11165-11174.

DOI: 10.1021/acs.inorgchem.8b01728

2.

F. Eustermann, S. Gausebeck, C. Dosche, M. Haensch, G. Wittstock, O. Janka
"Crystal Structure, Spectroscopic Investigations, and Physical Properties of the Ternary Intermetallic REPt2Al3 (RE = Y, Dy–Tm) and RE2Pt3Al4 Representatives (RE = Tm, Lu)"
Crystals 2018, 8, 169_1-169_20.

DOI: 10.3390/cryst8040169

1.

G. Tomaschun, W. Dononelli, Y. Li, M. Bäumer, T. Klüner, L. V. Moskaleva
"Methanol oxidation on the Au(3 1 0) surface: A theoretical study"
J. Catal. 2018, 364, 216-227.

DOI: 10.1016/j.jcat.2018.05.020

(Changed: 2021-09-20)