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Leitung
Prof. Dr. Jarl Ivar van der Vlugt

Mitglieder der Arbeitsgruppe

Sekretariat
Petra Rösner
W3 3-339
Tel: 0441 798 3654
FAX: 0441 798 3352
e-mail:  

Anreise Anschrift und Anfahrt

Journale

2020

120. Venderbosch, B., Oudsen, J.-P., van der Vlugt, J.I., Korstanje, T.J., Tromp, M.
Cationic copper iminophosphorane complexes as CuAAC catalysts: a mechanistic study
Organometallics 2020, 26, 3480-3489.

119.  van Leest, N.P., van der Vlugt, J.I., de Bruin, B.
Catalytic chemoselective sulfimidation with an electrophilic [CoIII(TAML)]-nitrene radical complex
Chem. Eur. J. 2020, 26, doi: 10.1002/chem.202003566.

118. van Leest, N.P., Stroek, W., Siegler, M.A., van der Vlugt, J.I.,  de Bruin, B.  
Ligand-mediated spin-state changes in a cobalt-dipyrrin-bisphenol complex
Inorg. Chem. 2020, 59, 12903-12912.

117. Wolzak, L.A., van der Vlugt, J.I., van den Berg, K., Reek, J.N.H , Tromp,  M., Korstanje, T.J.  
Titanium-catalyzed esterification reactions: beyond Lewis acidity
ChemCatChem 2020, 12, doi: 10.1002/cctc.202000931.       

116. Roeleveld, J.J. , Lekanne Deprez, S.J. , Verhoofstad, A., Frontera, A. , van der Vlugt, J.I., Mooibroek, T.J.   Engineering crystals using sp3–C centred tetrel bonding interactions
Chem. Eur. J. 2020, 26, doi: 10.1002/chem.202002613.                

115.  van Leest, N.P. ,  Tepaske, M.A. , Venderbosch, B., Oudsen,  J.-P., Tromp,  M. , van der Vlugt, J.I. ,de Bruin, B.
Electronically asynchronous transition states for C–N bond formation by electrophilic [CoIII(TAML)]-nitrene radical complexes involving substrate-to-ligand single-electron transfer and a cobalt-centered spin shuttle
ACS Catal. 2020, 10, 7449-7463.                                                     

114. Plessius, R. , Deij, V. , Reek,  J.N.H., van der Vlugt J.I.
Redox-active supramolecular heteroleptic M4L2L’2 assemblies with tunable interior binding site
Chem. Eur. J. 2020, 26, doi: 10.1002/chem.202001416.

113. Heywood, V.L. , Alford, T.P.J. , Roeleveld,  J.J. ,  Lekanne Deprez, S.J., Verhoofstad, A. ,  van der Vlugt,  J.I., Domingos, S.R. ,  Schnell, M. ,  Davis, A.P.,  Mooibroek, T.J.
Observations of tetrel bonding between sp3 carbon and THF
Chem. Sci. 2020, 11, 5289-5293.                                  

112. Zaffaroni, R. , Bobylev, E.O. , Plessius, R. ,  van der Vlugt, J.I.,  Reek, J.N.H.
Fundamental studies of electron transfer processes across the rim of M12L24 nano-spheres
J. Am. Chem. Soc. 2020, 142, 8837-8847.                   

111. Zhou, M. , Lankelma, M. , van der Vlugt, J.I., de Bruin,  B.
Catalytic synthesis of 8-membered ring compounds via cobalt(III)-carbene radicals
Angew. Chem. Int. Ed. 2020, 59, 11073-11079.            

110. Cornelissen, M.D. , Pilon,  S., Steemers,  L., Wanner, M.J. , Frölke, S. , Zuidinga, E., Ingemann Jørgensen, S. , van der Vlugt, J.I. , van Maarseveen, J.H.
Covalent and modular synthesis of homo and hetero [n]rotaxanes
Angew. Chem. Int. Ed. 2020, 59, 11073-11079.          

109. van Leest, N. P., Tepaske, M. A., Oudsen, J-P. H., Venderbosch, B., Rietdijk, N. R., Siegler, M. A., Tromp, M., van der Vlugt, J. I., de Bruin, B.
Ligand Redox Noninnocence in [Co-III(TAML)](0/-) Complexes Affects Nitrene Formation
J. Am. Chem.Soc. 2020, 142 (1), 552-563.
 

2019

108. Czauderna, C. F., Slawin, A. M. Z., Cordes, D. B., van der Vlugt, J. I., & Kamer, P. C. J.
P-stereogenic wide bite angle diphosphine ligands
Tetrahedron 2019, 75 (1), 47-56.

107. Devillard, M., Ehlers, A., Siegler, M. A., & van der Vlugt, J. I.
Selective Carbanion-Pyridine Coordination of a Reactive P,N Ligand to Rh-I
Chem. Eur. J.  2019, 25 (15), 3875-3883.

106. Gheorghe, A., Imaz, I., van der Vlugt, J. I., Maspoch, D., & Tanase, S.
Tuning the supramolecular isomerism of MOF-74 by controlling the synthesis conditions
Dalton Trans. 2019, 48 (27), 10043-10050.

105. Lankelma, M., Vreeken, V., Siegler, M. A., & van der Vlugt, J. I.
Dinuclear Gold Complexes Supported by Wide Bite Angle Diphosphines for Preorganization-Induced Selective Dual-Gold Catalysis
Inorganics 2019, 7 (3), [28].

104. Plessius, R., Orth, N., Ivanović-Burmazović, I., Siegler, M. A., Reek, J. N. H., & van der Vlugt, J. I.
Reversible multi-electron storage in dual-site redox-active supramolecular cages
Chem. Comm. 2019, 55 (84), 12619-12622.

103. Rebreyend, C., Mouarrawis, V., Siegler, M. A., van der Vlugt, J. I., & de Bruin, B.
Steric Protection of Rhodium-Nitridyl Radical Species
European Journal of Inorganic Chemistry 2019, (39-40), 4249-4255.

102. Schippers, E. C. F., Nurttila, S. S., Oudsen, J-PH., Tromp, M., Dzik, W. I., van der Vlugt, J. I., & Reek, J. N. H.
[FeFe]‐Hydrogenase Mimic Employing κ2C,N‐Pyridine Bridgehead Catalyzes Proton Reduction at Mild Overpotential
Eur. J. Inorg. Chem. 2019, (20), 2510-2517.

101. Zaffaroni, R., Dzik, W. I., Detz, R. J., van der Vlugt, J. I., & Reek, J. N. H.
Proton Relay Effects in Pyridyl-Appended Hydrogenase Mimics for Proton Reduction Catalysis
Eur. J. Inorg. Chem. 2019, (20), 2498-2509.

100. van Leest, N. P., Grooten, L., van der Vlugt, J. I., & de Bruin, B.
Uncatalyzed Oxidative C-H Amination of 9,10-Dihydro-9-Heteroanthracenes: A Mechanistic Study
Chem. Eur. J. 2019, 25 (23), 5987-5993.

99. van Vliet, K. M., Polak, L. H., Siegler, M. A., van der Vlugt, J. I., Guerra, C. F., & de Bruin, B.
Efficient Copper-Catalyzed Multicomponent Synthesis of N-Acyl Amidines via Acyl Nitrenes
J. .Am. Chem.Soc. 2019, 141 (38), 15240-15249.

98. van der Vlugt, J. I.
Radical-Type Reactivity and Catalysis by Single-Electron Transfer to or from Redox-Active Ligands
Chem. Eur. J. 2019, 25 (11), 2651-2662.
 

2018

97. Jongbloed, L. S., Vogt, N., Sandleben, A., de Bruin, B., Klein, A., & van der Vlugt, J. I.
Nickel-Alkyl Complexes with a Reactive PNC-Pincer Ligand
Eur. J. Inorg. Chem. 2018 (20-21), 2408-2418.

96. Zaffaroni, R., Detz, R. J., van der Vlugt, J. I., & Reek, J. N. H.
A Functional Hydrogenase Mimic Chemisorbed onto Fluorine-Doped Tin Oxide Electrodes: A Strategy towards Water Splitting Devices
ChemSusChem 2018, 11(1), 209-218.

95. te Grotenhuis, C., van den Heuvel, N., van der Vlugt, J. I., & de Bruin, B.
Catalytic Dibenzocyclooctene Synthesis via Cobalt(III)–Carbene Radical and ortho‐Quinodimethane Intermediates
Angew. Chem. Int. Ed. 2018, 57(1), 140-145.

94. te Grotenhuis, C., van den Heuvel, N., van der Vlugt, J. I., & de Bruin, B.
Catalytic Dibenzocyclooctene Synthesis via Cobalt(III)–Carbene Radical and ortho‐Quinodimethane Intermediates
Angew. Chem. 2018, 146-151.

93. van de Watering, F. F., Stroek, W., van der Vlugt, J. I., de Bruin, B., Dzik, W. I., & Reek, J. N. H.
Coordination of 3‐Methylindole‐Based Tripodal Tetraphosphine Ligands to Iron(+II), Cobalt(+II), and Nickel(+II) and Investigations of their Subsequent Two‐Electron Reduction
Eur. J. Inorg Chem. 2018 (11), 1254-1265.
 

2017

92. Bagh, B., Broere, D. L. J., Sinha, V., Kuijpers, P. F., van Leest, N. P., de Bruin, B., Demeshko, S., Siegler, M.A., van der Vlugt, J. I.
Catalytic Synthesis of N-Heterocycles via Direct C(sp3)–H Amination Using an Air-Stable Iron(III) Species with a Redox-Active Ligand
J. Am. Chem. Soc.  2017, 139 (14), 5117-5124.

91. Devillard, M., de Bruin, B., Siegler, M. A., van der Vlugt, J. I.
Transition-Metal-Free Cleavage of CO
Chem. Eur. J.  2017, 23 (55), 13628-13632.

90. Kuijpers, P. F., Tiekink, M. J., Breukelaar, W. B., Broere, D. L. J., van Leest, N. P., van der Vlugt, J. I., Reek, J.N.H., de Bruin, B.
Cobalt-Porphyrin-Catalysed Intramolecular Ring-Closing C-H Amination of Aliphatic Azides: A Nitrene-Radical Approach to Saturated Heterocycles
Chem. Eur. J.  2017, 23 (33, SI), 7945-7952.

89. Kuijpers, P. F., van der Vlugt, J. I., Schneider, S., de Bruin, B.
Nitrene Radical Intermediates in Catalytic Synthesis
Chem. Eur. J.  2017, 23 (56), 13819-13829.

88. Rebreyend, C., Gloaguen, Y., Lutz, M., van der Vlugt, J. I., Siewert, I., Schneider, S., de Bruin, B.
Electrocatalytic Azide Oxidation Mediated by a Rh(PNP) Pincer Complex
Chem. Eur. J.  2017, 23 (69), 17438-17443.

87.Sluijter, S. N., Korstanje, T. J., van der Vlugt, J. I., Elsevier, C. J.
Mechanistic insights into catalytic carboxylic ester hydrogenation with cooperative Ru(II)-bis1,2,3-triazolylidene pyridine pincer complexes
J. Org. Chem. 2017, 845, 30-37.

86. Vreeken, V., Baij, L., de Bruin, B., Siegler, M. A.,  van der Vlugt, J. I.
N-Atom transfer via thermal or photolytic activation of a Co-azido complex with a PNP pincer ligand
Dalton Trans. 2017, 46 (22), 7145-7149.

85.Vreeken, V., Siegler, M. A., van der Vlugt, J. I.
Controlled Interconversion of a Dinuclear Au Species Supported by a Redox-Active Bridging PNP Ligand Facilitates Ligand-to-Gold Electron Transfer
Chem. Eur. J.  2017, 23 (23), 5585-5594.

84. de Boer, S. Y., Korstanje, T. J., La Rooij, S. R., Kox, R., Reek, J. N. H., van der Vlugt, J. I.
Ruthenium PNN(O) Complexes: Cooperative Reactivity and Application as Catalysts for Acceptorless Dehydrogenative Coupling Reactions
Organometallics 2017, 36 (8), 1541-1549.

83. van de Watering, F. F., Heijtbrink, N., van der Vlugt, J. I., Dzik, W. I., de Bruin, B., Reek, J. N. H.
3-Methylindole-Based Tripodal Tetraphosphine Ruthenium Complexes in N2 Coordination and Reduction and Formic Acid Dehydrogenation
Inorganics 2017, 5 (4), [73].

82. van de Watering, F. F., van der Vlugt, J. I., Dzik, W. I., de Bruin, B., Reek, J. N. H.
Metalloradical Reactivity of RuI and Ru0 Stabilized by an Indole-Based Tripodal Tetraphosphine Ligand
Chem. Eur. J.  2017, 23 (52), 12709-12713.                   
 

2016

81. D.L.J. Broere, N.P. van Leest, B. de Bruin, J.I. van der Vlugt
Reversible redox chemistry and catalytic C(sp3)-H amination reactivity of a paramagnetic Pd complex bearing a redox-active o-aminophenol-derived NNO pincer ligand
Inorg. Chem. 2016, 5517, 8603–8611.

80.  L.S. Jongbloed, D. García-López, R. van Heck, M.A. Siegler, J.J. Carbo, J.I. van der Vlugt
Arene C(sp2)-H metalation at NiII modeled with a reactive PONCPh ligand
Inorg. Chem. 2016, 5516, 8041–8047.

79. D.L.J. Broere, R. Plessius, J. Tory, S. Demeshko, B. de Bruin, M.A. Siegler, F. Hartl, J.I. van der Vlugt
Ligand-based mixed-valence in a triazole-bridged dinuclear palladium complex
Chem. Eur. J. 2016, 22, 39, 13965-13975.

78. V. Vreeken, D.L.J. Broere, A.C.H. Jans, M. Lankelma, J.N.H. Reek, M.A. Siegler, J.I. van der Vlugt
Dinuclear Au-complexes supported by a single ligand framework
Angew. Chem. Int. Ed. 2016, 55, 34, 10042-10046.

77. M. Devillard, C. Alvarez Lamsfus, V. Vreeken, L. Maron, J.I. van der Vlugt
Versatile coordination of a reactive P,N-ligand toward boron, aluminum and gallium
Dalton Trans. 2016, 45, 10989-10998.

76. B. Bagh, D.L.J. Broere, M.A. Siegler, J.I. van der Vlugt
Redox-active ligand mediated formation of an acyclic trinuclear ruthenium complex with bridging nitrido ligands
Angew. Chem. Int. Ed. 2016, 55, 8381-8385.

75. Z. Tang, C. Tejel, M. Lutz, J.I. van der Vlugt, B. de Bruin
Redox-chemistry of iminopyridyl ligands in Rh(I)- and Ir(I)-complexes
Eur. J. Inorg. Chem. 2016, 963-974.
 
74. D.L.J. Broere, D.K. Modder, E. Blokker, M.A. Siegler, J.I. van der Vlugt
Metal-metal interactions in heterobimetallic complexes with dinucleating redox active ligands
Angew. Chem. Int. Ed. 2016, 55, 2452-2456.

73. L.S. Jongbloed, B. de Bruin, J.N.H. Reek, M. Lutz, J.I. van der Vlugt
Base-free formic acid dehydrogenation via reversible cyclometalation (inside front cover)
Catal. Sci. Technol. 2016, 6, 1320-1327.

72. S. Oldenhof, J.I. van der Vlugt, J.N.H. Reek
Hydrogenation of CO2 to formic acid with iridiumIII(bisMETAMORPhos)(hydride): the role of a dormant fac-IrIII(trihydride) and an active trans-IrIII(dihydride) species
Catal. Sci. Technol. 2016, 6, 404-408.

2015

71. A.E. Pascui, K. van Rees, D.W. Zant, D.L.J. Broere, M.A. Siegler, J.I. van der Vlugt
Platinum(II) metallamacrocycles with a ditopic diphosphine ligand
Eur. J. Inorg. Chem. 2015, 5687-5693.

70.Z. Tang, M. Lutz, J.I. van der Vlugt, B. de Bruin
Rh-catalyzed conversion of carbenes into ketenes and ketene imines
Org. Chem. Front. 2015, 2, 1561-1577.

69. T.J. Korstanje, J.I. van der Vlugt, C.J. Elsevier, B. de Bruin
Hydrogenation of carboxylic acids with a homogeneous cobalt catalyst
Science 2015, 350, 298-302.

68. S. Oldenhof, M. Lutz, J.I. van der Vlugt, J.N.H. Reek
Intermolecular C-H activation with an Ir-METAMORPhos piano-stool complex – Multiple reaction steps at a reactive ligand
Chem. Commun. 2015, 51, 15200-15203.
                                                                  
67. D.L.J. Broere, R. Plessius, J.I. van der Vlugt
New avenues for ligand-mediated processes – Expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands
Chem. Soc. Rev. 2015, 44, 6886-6915.

66. Z. Tang, E. Otten, J.N.H. Reek, J.I. van der Vlugt, B. de Bruin
Dynamic ligand reactivity in a rhodium pincer complex (front cover)
Chem. Eur. J. 2015, 21, 12683-12693.
Hot Paper

65. S. Oldenhof, F.G. Terrade, M.Lutz, J.I. van der Vlugt, J.N.H. Reek
Formation and site-selective reactivity of a nonsymmetric dinuclear iridium bisMETAMORPhos complex
Organometallics 2015, 34, 3209-3215.

64. V. Vreeken, M. Lutz, B. de Bruin, J. N. H. Reek, M.A. Siegler, J.I. van der Vlugt
Efficient C-H activation of arenes by a photoactivated NiII(azide) – Formation of a transient nickel nitrido complex
Angew. Chem. Int. Ed. 2015, 54, 7055-7059.

63. L.S. Jongbloed, B. de Bruin, J.N.H. Reek, M. Lutz, J.I. van der Vlugt
Facile synthesis and versatile reactivity of an unusual cyclometalated RhI pincer complex
Chem. Eur. J. 2015, 21, 7297-7305.

62. C.F. Czauderna, A.G. Jarvis, F.J.L. Heutz, D.B. Cordes, A.M.Z. Slawin, J.I. van der Vlugt, P.C.J. Kamer
Chiral wide bite angle diphosphine ligands: Synthesis, coordination chemistry and application in Pd-catalyzed allylic alkylation
Organometallics 2015, 34, 1608-1618.
                                                      
61. D.L.J. Broere, S. Demeshko, B. de Bruin, E.A. Pidko, J.N.H. Reek, M. Lutz, M.A. Siegler, J.I. van der Vlugt
Dinuclear palladium complexes with two ligand-centered radicals and a single bridging ligand: Subtle tuning of magnetic properties
Chem. Eur. J. 2015, 21, 5879-5886.

60. H.-C. Chen, D.G.H. Hetterscheid, R. Williams, J.I. van der Vlugt, J.N.H. Reek, A.M. Brouwer
Platinum(II)-porphyrin as a sensitizer for visible light-driven water oxidation in neutral phosphate buffer solution
Energy Environ. Sci. 2015, 8, 975-982.

59. S. Oldenhof, M. Lutz, B. de Bruin, J.I. van der Vlugt, J.N.H. Reek
Formic acid dehydrogenation by Ir-bisMETAMORPhos complexes: Experimental and computational insight in the role of a cooperative ligand acting as H-bond acceptor
Chem. Sci. 2015, 6, 1027-1034.

58. D.L.J. Broere, L.L. Metz, B. de Bruin, J.N.H. Reek, M.A. Siegler, J.I. van der Vlugt
Redox-active ligand-induced homolytic bond activation
Angew. Chem. Int. Ed. 2015, 54, 1516-1520.

57. M. Nasalevich, R. Becker, E.V. Ramos-Fernandez, S. Castellanos, S.L. Veber, M.V. Fedin, F. Kapteijn, J.N.H. Reek, J.I. van der Vlugt, J. Gascon
Cobaloxime encapsulation in a photo-active metal-organic framework for light-driven H2 production
Energy Environ. Sci. 2015, 8, 364-375.

2014

56.  S. Oldenhof, M. Lutz, B. de Bruin, J.I. van der Vlugt, J.N.H. Reek
A well-defined bisMETAMORPhos PdI-PdI complex: Synthesis, structural characterization and reactivity
Organometallics 2014, 33, 7293-7298.

55. D.L.J. Broere, B. de Bruin, J.N.H. Reek, M. Lutz, S. Dechert, J.I. van der Vlugt
Intramolecular redox-active ligand-to-substrate single electron transfer: Radical reactivity with a palladium(II) complex (front cover)
J. Am. Chem. Soc. 2014, 136, 11574-11577. 
JACS Spotlights highlight

54.  Y. Gloaguen, C. Rebreyend, M. Lutz, P. Kumar, M.I. Huber, J.I. van der Vlugt, S. Schneider, B. de Bruin
An isolated ‘nitridyl-radical’ bridged RhN•Rh complex
Angew. Chem. Int. Ed. 2014, 53, 6814-6818.

53. F.G. Terrade, M. Lutz, J.I. van der Vlugt, J.N.H. Reek
Synthesis, coordination chemistry and cooperative activation of H2 with ruthenium complexes of proton-responsive METAMORPhos ligands
Eur. J. Inorg. Chem. 2014, 1826-1835.
invited articleissue ‘Advances in Phosphorus Chemistry’

52. S.H. Chikkali, J.I. van der Vlugt, J.N.H. Reek
Hybrid diphosphorus ligands in Rh catalyzed asymmetric hydroformylation
Coord. Chem. Rev. 2014, 262, 1-15. 

51. C.F. Czauderna, D.B. Cordes, A.M.Z. Slawin, C. Müller, J.I. van der Vlugt, D. Vogt, P.C.J. Kamer
Synthesis and reactivity of chiral wide bite angle hybrid diphosphorus ligands
Eur. J. Inorg. Chem. 2014, 1797-1810.

2013

50. A.I. Olivos Suarez, V. Lyaskovskyy, J.N.H. Reek, J.I. van der Vlugt, B. de Bruin
Nitrogen centered ligand radical complexes: Classification, spectroscopic features, reactivity and catalytic applications
Angew. Chem. Int. Ed. 2013, 52, 12510-12529.

49. Y. Gloaguen, L.M. Jongens, J.N.H. Reek, M. Lutz, B. de Bruin, J.I. van der Vlugt*
Reductive elimination at an orthometalated IrIII hydride bearing a tripodal tetraphosphorus ligand

Organometallics 2013, 32, 4284-4291.

48. S. Oldenhof, B. de Bruin, M. Lutz, M.A. Siegler, F.W. Patureau, J.I. van der Vlugt, J.N.H. Reek
Base-free production of H2 by dehydrogenation of formic acid using an iridium-bisMETAMORPhos complex
Chem. Eur. J. 2013, 19, 11507-11511.

47. A.M. Kluwer, C. Simons, Q. Knijnenburg, J.I. van der Vlugt, B. de Bruin, J.N.H. Reek
Catalyst recycling via specific non-covalent adsorption on modified silicas
Dalton Trans. 2013, 42, 3609-3616.

46. Y. Gloaguen, W. Jacobs, B. de Bruin, M. Lutz, J.I. van der Vlugt*
Reactivity of a mononuclear IrI species bearing a terminal phosphido fragment embedded in a triphosphorus ligand

Inorg. Chem. 2013, 52, 1682-1684.

45. A. Perrier, M. Ferreira, J.N.H. Reek, J.I. van der Vlugt*
Regioselective Pd-catalyzed hydroamination of substituted dienes

Catal. Sci. Technol. 2013, 3, 1375-1379.

44.  B. van den Bosch, H.-C. Chen, J.I. van der Vlugt, A.M. Brouwer, J.N.H. Reek
A noble-metal free system for photocatalytic proton reduction
ChemSusChem 2013, 6, 790-793.

2012

43.  S.Y. de Boer, Y. Gloaguen, J.N.H. Reek, M. Lutz, J.I. van der Vlugt*
N-H bond activation by palladium(II) and copper(I) complexes featuring a cooperative bidentate PN-ligand
(front cover)
Dalton Trans. 2012, 41, 11276-11283.

42.  S.H. Chikkali, R. Bellini, B. de Bruin, J.I. van der Vlugt, J.N.H. Reek
Highly selective asymmetric Rh-catalyzed hydroformylation of heterocyclic olefins
J. Am. Chem. Soc. 2012, 134, 6607-6616.

41. R. Bellini, J.I. van der Vlugt, J.N.H. Reek
Supramolecular asymmetric catalysis
Isr. J. Chem. 2012, 52, 613-629.

40. S.Y. de Boer, Y. Gloaguen, M. Lutz, J.I. van der Vlugt*
CuI click catalysis with cooperative noninnocent pyridylphosphine ligands

Inorg. Chim. Acta 2012, 380, 336-342.
invited articleissue ‘Inorganic Chemistry – the Next Generation’
          
39. J.I. van der Vlugt*
First row transition metal cooperative catalysis (front cover)   
Eur. J. Inorg. Chem. 2012, 363-375.
invited micro-reviewissue ‘Cooperative & Redox Noninnocent Ligands’
top-3 most cited articles of 2011-2012 & top-10 most accessed articles 06/2013-12/2015

2011

38. R.C. Bauer, Y. Gloaguen, M. Lutz, J.N.H. Reek, B. de Bruin, J.I. van der Vlugt*
Pincer ligands with an all-phosphorus donor set: Subtle differences between rhodium and palladium

Dalton Trans. 2011, 40, 8822-8829.
invited articleissue ‘Pincers and other Hemilabile Ligands’

37. J.I. van der Vlugt,* E.A. Pidko, R.C. Bauer, Y. Gloaguen, M.K. Rong, M. Lutz
Dinuclear CuI thiolate complexes with a bridging noninnocent PNP-ligand
Chem. Eur. J. 2011, 17, 3850-3854.

36.  W.I. Dzik, J.I. van der Vlugt, J.N.H. Reek, B. de Bruin
Ligands that store & release electrons during catalysis
Angew. Chem. Int. Ed. 2011, 50, 3356-3358.

35. R. Lindner, B. van den Bosch, M. Lutz, J.N.H. Reek, J.I. van der Vlugt*
Tunable hemilabile ligands for adaptive late transition metal complexes

Organometallics 2011, 30, 499-510.

2010

34. J. Wassenaar, M.A. Siegler, A.L. Spek, B. de Bruin, J.N.H. Reek, J.I. van der Vlugt
Versatile new C3-symmetric tripodal tetraphosphine ligands; Structural flexibility to stabilize CuI and RhI species and their reactivity
Inorg. Chem. 2010, 49, 6495-6508.

33. S.H. Chikkali, R. Bellini, G. Berthon-Gelloz, J.I. van der Vlugt, B. de Bruin, J.N.H. Reek
Highly enantioselective hydroformylation of dihydrofurans catalyzed by hybrid phosphine-phosphonite rhodium complexes
Chem. Commun. 2010, 46, 1244-1246.

32. J.I. van der Vlugt
Advances in selective activation and application of ammonia in homogeneous catalysis
Chem. Soc. Rev. 2010, 39, 2302-2322.
invited critical review

31. J.I. van der Vlugt
Boryl based pincer ligands: New avenues in boron chemistry
Angew. Chem. Int. Ed. 2010, 49, 252-255.
invited highlight

30. J. Wassenaar, B. de Bruin, M.A. Siegler, A.L. Spek, J.N.H. Reek, J.I. van der Vlugt
Activation of H2 by a highly distorted RhII complex with a new C3-symmetric tripodal tetraphosphine ligand
Chem. Commun. 2010, 46, 1232-1234.

2009

29. J.I. van der Vlugt, J.N.H. Reek
Neutral tridentate PNP ligands and their hybrid analogues: Versatile (non-innocent) scaffolds for homogeneous catalysis
Angew. Chem. Int. Ed. 2009, 48, 8832-8846.
invited minireview

28. D.G.H. Hetterscheid, J.I. van der Vlugt, B. de Bruin, J.N.H. Reek
Water splitting via cooperative catalysis
Angew. Chem. Int. Ed. 2009, 48, 8178-8181.

27.  J.I. van der Vlugt, E.A. Pidko, D. Vogt, M. Lutz, A.L. Spek
CuI complexes with a non-innocent CuI(PNP) complex: Selective dearomatization and electrophilic addition reactivity
Inorg. Chem. 2009, 48, 7513-7515.

26. J.I. van der Vlugt, M.A. Siegler, M. Janssen, D. Vogt, A.L. Spek
A cationic AgI(PNPtBu) species acting as PNP transfer agent: Facile synthesis of Pd(PNPtBu)(alkyl) complexes and their reactivity compared to PCPtBu analogues
Organometallics 2009, 28, 7025-7032.

25. M.M.P. Grutters, J.I. van der Vlugt, Y. Pei, A.M. Mills, M. Lutz, A.L. Spek, C. Müller, C. Moberg, D. Vogt
Highly selective cobalt-catalyzed hydrovinylation of vinylarenes
Adv. Synth. Catal. 2009, 351, 2199-2208.

25. A. Kumar Singh, J.I. van der Vlugt, S. Demeshko, S. Dechert, F. Meyer
Dinuclear complexes with functionalized pyrazolate ligands
Eur. J. Inorg. Chem. 2009, 3431-3439.

23. M. Lutz, J.I. van der Vlugt, D. Vogt, A.L. Spek
Solid-solid phase transition in [Ni(OAc)(PNPtBu)]OTf leading to six independent molecules in the asymmetric unit
Polyhedron 2009, 28, 2341-2346.

22. J.I. van der Vlugt, M. Lutz, E.A. Pidko, D. Vogt, A.L. Spek
Cationic and neutral NiII complexes derived from a non-innocent PNP ligand: Formation of alkyl and thiolate species and their reactivity
Dalton Trans. 2009, 1016-1023.

2008

21.  J.I. van der Vlugt, E.A. Pidko, D. Vogt, M. Lutz, A.L. Spek, A. Meetsma        
T-shaped cationic CuI complexes with hemilabile PNP-type ligands
Inorg. Chem. 2008, 47, 4442-4444.

21.  J.I. van der Vlugt, S. Demeshko, S. Dechert, F. Meyer
Tetranuclear CoII, MnII and CuII complexes of a novel binucleating pyrazolate ligand preorganized for the self-assembly of compact [2´2] grid structures
Inorg. Chem. 2008, 47, 1576-1585.

2007

19. R. van Duren, J.I. van der Vlugt, A.M. Mills, A.L. Spek, D. Vogt
Platinum-catalyzed hydroformylation of terminal and internal octenes
Dalton Trans. 2007, 1053-1059.

18. A.K. Justice, G. Zampella, L. de Goia, T.B. Rauchfuss, J.I. van der Vlugt, S.R. Wilson
Chelate control of diiron(I) dithiolates relevant to the Fe-only hydrogenase active site
Inorg. Chem. 2007, 46, 1655-1664.

2006

17. R. van Duren, L.J.J.M. Cornelissen, J.I. van der Vlugt, J.P.J. Huibers, A.M. Mills, A.L. Spek, C. Müller, D. Vogt
Chiral diphosphonite platinum complexes in asymmetric hydroformylation
Helv. Chim. Acta 2006, 89, 1547-1558.

16.  J.I. van der Vlugt, T.B. Rauchfuss, S.R. Wilson
Electron-rich diferrous-phosphane-thiolates relevant to Fe-only hydrogenase: Is cyanide “nature's trimethylphosphane”?
Chem. Eur. J. 2006, 12, 90-98.

2005

15. G. Ionescu, J.I. van der Vlugt, H.C.L. Abbenhuis, D. Vogt  
Synthesis and applications of chiral phosphite ligands derived from incompletely condensed silsesquioxane backbones    
Tetrahedron: Asymmetry 2005, 16, 3970-3975.

14.  J.I. van der Vlugt, T.B. Rauchfuss, C.M. Whaley, S.R. Wilson
Characterization of a diferrous terminal hydride mechanistically relevant to the Fe-only hydrogenases
J. Am. Chem. Soc. 2005, 127, 16012-16013.

13. J.I. van der Vlugt, R. van Duren, G.D. Batema, R. den Heeten, A. Meetsma, J. Fraanje, K. Goubitz, P.C.J. Kamer, P.W.N.M. van Leeuwen, D. Vogt
Platinum complexes of rigid bidentate phosphine ligands in the hydroformylation of 1-octene
Organometallics 2005, 24, 5377-5382.

12. C.A. Boyke, J.I. van der Vlugt, T.B. Rauchfuss, S.R. Wilson, G. Zampella, L. de Gioia
Diferrous cyanides as models for the Fe-only hydrogenases
J. Am. Chem. Soc. 2005, 127, 11010-11018. 

11. R. Sablong, J.I. van der Vlugt, R. Thomann, S. Mecking, D. Vogt
Disperse amphiphilic submicron particles as non-covalent supports for cationic homogeneous catalysts
Adv. Synth. Catal. 2005, 347, 633-636.

10. E.J. Zijp, J.I. van der Vlugt, D.M. Tooke, A.L. Spek, D. Vogt
Chiral bidentate aminophosphine ligands: Synthesis, coordination chemistry and asymmetric catalysis
Dalton Trans. 2005, 512-517.

2004

9.  J.I. van der Vlugt, J.M.J. Paulusse, E.J. Zijp, J.A. Tijmensen, A.M. Mills, A.L. Spek, C. Claver, D. Vogt
Coordination chemistry and asymmetric catalysis with a chiral diphosphonite
Eur. J. Inorg. Chem. 2004, 4193-4201.

8. J.I. van der Vlugt, A.C. Hewat, S. Neto, R. Sablong, A.M. Mills, A.L. Spek, C. Müller, D. Vogt
Sterically demanding diphosphonite ligands – synthesis and application in nickel catalyzed isomerization of 2-methyl-3-butenenitrile
Adv. Synth. Catal. 2004, 346, 993-1003.

7. J.I. van der Vlugt, R. Sablong, P.C.M.M. Magusin, A.M. Mills, A.L. Spek, D. Vogt
Rhodium complexes of sterically constrained diphosphonites – coordination chemistry and catalysis
Organometallics 2004, 23, 3177-3183.

6.  J.I. van der Vlugt, J. Ackerstaff, T.W. Dijkstra, A.M. Mills, H. Kooijman, A.L. Spek, A. Meetsma, H.C.L. Abbenhuis, D. Vogt
Versatile phosphite ligands based on silsesquioxane backbones
Adv. Synth. Catal. 2004, 346, 399-412.

2003

5.  J.I. van der Vlugt, R. Sablong, A.M. Mills, H. Kooijman, A.L. Spek, A. Meetsma, D. Vogt
Coordination chemistry and X-ray studies with novel sterically constrained diphosphonite ligands
Dalton Trans. 2003, 4690-4699.

4.  J.I. van der Vlugt, M. Fioroni, J. Ackerstaff, R.W.J.M. Hanssen, A.M. Mills, A.L. Spek, A. Meetsma, H.C.L. Abbenhuis, D. Vogt
A silsesquioxane-based diphosphinite ligand – synthesis, DFT study and coordination chemistry
Organometallics 2003, 22, 5297-5306.

3. J.I. van der Vlugt, M.M.P. Grutters, A.M. Mills, H. Kooijman, A.L. Spek, D. Vogt
New diphosphane ligands based on bisphenol A backbones - synthesis and coordination chemistry
Eur. J. Inorg. Chem. 2003, 4361-4369.

2. J.I. van der Vlugt, M.M.P. Grutters, J. Ackerstaff, R.W.J.M. Hanssen, H.C.L. Abbenhuis, D. Vogt
POSSphites – monophosphites derived from incompletely condensed silsesquioxanes
Tetrahedron Lett. 2003, 44, 8301-8305.

1. J.I. van der Vlugt, J.M. Bonet, A.M. Mills, A.L. Spek, D. Vogt
Modular diphosphine ligands based on bisphenol A backbones
Tetrahedron Lett. 2003, 44, 4389-4392.

(Stand: 18.11.2020)